Iridium complexes
Johnson Matthey offers a selection of iridium complexes for various applications. JM鈥檚 iridium complex products can be combined with a variety of ligand classes such as phosphines, cyclopentadienyls, NHCs and polypyridyl ligands to form active Ir catalysts for a variety of applications. Example applications include asymmetric hydrogenation (1), asymmetric C-C and C-N bond formation, cyclometallation, direct C-H borylation (2) and photoredox catalysis (3).
References:
- 1. Kim, A. N. and Stoltz, B.M. ACS Catalysis 2020 10 (23), 13834-13851.
- 2. (a) Slack, E.D. and Colacot, T.J. Organic Letters鈥�2021鈥�23鈥�(5), 1561-1565; (b) D鈥橝ngelo, K.A.; La, C.; Kotecki, B.;Wilson, J.W.; Karmel, C.; Swiatowiec, R.; Tu, N. P.; Shekhar, S. and
- Hartwig,F.J. J. Am. Chem. Soc. 2024 146 (47), 32717-32729
- 3. Shaw, M.H.; Twilton, J. and MacMillan, D. W. C. J. Org. Chem. 2016 81 (16), 6898-6926
Iridium complex options
滨谤(补肠补肠)鈧�
Product number: Ir-70
CAS number: 15635-87-7
Mol weight: 489.54
Reaction type: hydrogenation
CAS number: 15635-87-7
Mol weight: 489.54
Reaction type: hydrogenation
Crabtree's catalyst, [Ir(cod)py(PCy鈧�)]PF鈧�
Product number: Ir-90
CAS number: 64536-78-3
Mol weight: 804.9
Reaction type: hydrogenation
CAS number: 64536-78-3
Mol weight: 804.9
Reaction type: hydrogenation
摆滨谤颁濒(肠辞别)鈧俔鈧�
Product number: Ir-91
CAS number: 12246-51-4
Mol weight: 896.14
Reaction type: Hartwig borylation, hydrogenation, C-H activation
CAS number: 12246-51-4
Mol weight: 896.14
Reaction type: Hartwig borylation, hydrogenation, C-H activation
摆滨谤(翱惭别)(肠辞诲)闭鈧�
Product number: Ir-92
CAS number: 12148-71-9
Mol weight: 662.87
Reaction type: Hartwig borylation, hydrogenation, C-H activation
CAS number: 12148-71-9
Mol weight: 662.87
Reaction type: Hartwig borylation, hydrogenation, C-H activation
摆滨谤颁濒(肠辞诲)闭鈧�
Product number: Ir-93
CAS number: 12112-67-3
Mol weight: 671.71
Reaction type: Hartwig borylation, hydrogenation, C-H activation
CAS number: 12112-67-3
Mol weight: 671.71
Reaction type: Hartwig borylation, hydrogenation, C-H activation
摆滨谤(肠辞诲)(辫丑别苍)闭颁濒鈥贬贵
Product number: Ir-94
CAS number: 41396-69-4
Mol weight: 516.06
Reaction type: Hartwig borylation, C-H activation
CAS number: 41396-69-4
Mol weight: 516.06
Reaction type: Hartwig borylation, C-H activation
摆滨谤(肠辞诲)(惭别鈧刾丑别苍)闭颁濒鈥贬贵
Product number: Ir-95
CAS number: 3031475-00-7
Mol weight: 644.28
Reaction type: Hartwig borylation, C-H activation
CAS number: 3031475-00-7
Mol weight: 644.28
Reaction type: Hartwig borylation, C-H activation
摆滨谤(颁辫*)颁濒鈧俔鈧�
Product number: Ir-115
CAS number: 12354-84-6
Mol weight: 796.71
Reaction type: hydrogenation, assymetric catalysis, C-H activation
CAS number: 12354-84-6
Mol weight: 796.71
Reaction type: hydrogenation, assymetric catalysis, C-H activation
Ir(acac)(cod)
Product number: Ir-116
CAS number: 12154-84-6
Mol weight: 399.51
Reaction type: hydrogenation, asymmetric catalysis, C-H activation
CAS number: 12154-84-6
Mol weight: 399.51
Reaction type: hydrogenation, asymmetric catalysis, C-H activation
摆滨谤(肠辞诲)鈧俔叠贵鈧�
Product number: Ir-118
CAS number: 35138-23-9
Mol weight: 495.39
Reaction type: hydrogenation, asymmetric catalysis, C-H activation
CAS number: 35138-23-9
Mol weight: 495.39
Reaction type: hydrogenation, asymmetric catalysis, C-H activation
摆滨谤(颁辫*)濒鈧俔鈧�
Product number: Ir-121
CAS number: 33040-12-9
Mol weight: 1162.5
Reaction type: hydrogenation, asymmetric catalysis, C-H activation
CAS number: 33040-12-9
Mol weight: 1162.5
Reaction type: hydrogenation, asymmetric catalysis, C-H activation
滨谤(颁鈧圚鈧佲倐)调笔颁贬鈧�(颁鈧咹鈧�)鈧仓鈧侾贵鈧�
Product number: Ir-123
CAS number: 38465-86-0
Mol weight: 845.81
Reaction type: hydrogenation
CAS number: 38465-86-0
Mol weight: 845.81
Reaction type: hydrogenation
摆滨谤(辫辫测(鈧�(诲迟产产辫测)闭摆笔贵鈧哴
Product number: Ir-125
CAS number: 676525-77-2
Mol weight: 913.95
Reaction type: photocatalysis
CAS number: 676525-77-2
Mol weight: 913.95
Reaction type: photocatalysis
摆滨谤调诲贵(颁贵鈧�)辫辫测皑鈧�(诲迟产产辫测)闭摆笔贵鈧哴
Product number: Ir-126
CAS number: 870987-63-6
Mol weight: 1121.91
Reaction type: photocatalysis
CAS number: 870987-63-6
Mol weight: 1121.91
Reaction type: photocatalysis
IrCl(cod)(dppe)
Product number: Ir-127
CAS number: 688063-93-6
Mol weight: 734.38
Reaction type: hydrogenation
CAS number: 688063-93-6
Mol weight: 734.38
Reaction type: hydrogenation